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Dibenzo[a,c]phenazine-Based Donor-Acceptor (D-A) Tetra Branched Molecules: Fine Tuning of Optical Properties

机译:Dibenzo [a,c]基于苯嗪的供体供应器(D-A)四型分子:光学性质的微调

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摘要

Four dibenzo[a,c]phenazine based donor-acceptor tetra branched molecules were synthesized. The optical (including absorption, steady state and time resolved fluorescence) and electrochemical properties of these compounds were investigated. The emitting behavior of these molecules depends on the donor strength of the side-arms. Tuning of optical properties has been performed by varying side-arms. Electron deficient 4-(2-benzothiazolyl)phenyl side-arm compound emit light in the blue region. Weak donor (4-methoxyphenyl substituted) compound shows red shifted emission in green region. With strong donor (thiophene and triphenylamine) substituted compounds exhibits red and orange-red emission respectively.
机译:合成了四个二苯二[A,C]基于苯嗪的供体 - 受体四枝分子。 研究了这些化合物的光学(包括吸收,稳态和时间分辨荧光)和电化学性能。 这些分子的发射行为取决于侧臂的供体强度。 光学性质的调整已通过不同的侧臂进行。 电子缺乏4-(2-苯甲噻唑基)苯基侧臂化合物在蓝色区域发出光。 弱供体(4-甲氧基苯基取代)化合物在绿色区域显示出红色的发射。 具有强大的供体(噻吩和三苯胺)取代的化合物分别表现出红色和橙红色的发射。

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