Nuclear Magnetic Resonance Characterization of Renewable Products from a Two-Step Ex-Situ Hydropyrolysis Vapor Upgrading Process

摘要

A novel two-step ex-situ hydropyrolysis vapor upgrading (HPVU) process can generate tailored oxygenated hydrocarbon products from lignocellulosic biomass by adjusting vapor upgrading temperature. Such products, containing varied oxygen contents (ranging from 2 to 17 wt%), are different from traditional petroleum hydrocarbons and conventional biomassderived pyrolysis oil. Elucidation of the comprehensive structural motif of these unconventional products is critical for development and deployment of the HPVU process. To this end, two-dimensional heteronuclear ~1H-~(13)CNMR techniques were employed to first provide single- and multiple-bond correlations between protons and carbons characteristic of different organic functional groups. The distribution of carbon functional groups was further determined by quantitative ~(13)CNMR spectroscopy with full relaxation and well-defined chemical shift regions obtained from diverse NMR methods. Phenols and ketones were identified as the main oxygenate species in these renewable products. At higher vapor upgrading temperatures, a decrease in oxygenate species and an increase in alkylation on aromatic rings were observed. Of particular importance, compared to pyrolysis oil, the amounts of thermally unstable oxygenate species, such as aldehyde, carboxylic acid, and carbohydrate, were found to be minimal, suggesting good thermal stability of these renewable hydrocarbon products.