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Silver Nanoparticles Embedded Graphene Oxide Nanocomposite with Enhanced Antibacterial and Photocatalytic Degradation Activities

机译:银纳米颗粒嵌入氧化石墨烯纳米复合材料,具有增强的抗菌和光催化降解活性

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Silver nanoparticles embedded graphene oxide (Ag-GO) nano- composite was prepared by one pot synthesis technique. The pristine composite was analyzed via FESEM, TEM, EDX, XPS and Raman spectroscopy. The nanocomposite exhibits enhanced photocatalytic and antibacterial activities with improved bio- compatibility. Owing to synergy, Ag-GO composite inhibits growth and multiplication of the tested bacteria, Escherichia coli and Methicillin-resistant Staphylococcus aureus, in the first 2 h and then ceases their growth completely up to 24 h. The cell viability was found to be 85% for Ag-GO doses up to 160 ppm tested with human corneal epithelial cells, which indicates the nontoxic behavior of the composite. Moreover, Ag-GO nanocomposite exibits enhanced photocatalytic degradation properties for toxic organic dyes. The composite shows 98% degradation of rhodamine B in 24 min, 97% of methylene blue in 14 min and 99% of commercial dye-AY in 12 min. The photocatalytic efficiency was found to be about five times higher than that of the pure GO. During the photocatalytic process the reactive oxygen species (ROS) generated via surface plasmon resonance of Ag nanoparticles are responsible for the good bacterial population control as well as for the enhanced photocatalytic degradation activity. The reusability and recyclability of Ag-GO nanocomposite suggest its commer- cial utilization with structural stability and good biocompati- bility.
机译:银纳米颗粒嵌入了氧化石墨烯(AG-GO)纳米复合材料是通过一种锅合成技术制备的。通过FESEM,TEM,EDX,XP和拉曼光谱法分析了原始复合材料。纳米复合材料表现出增强的光催化和抗菌活性,具有提高的生物兼容性。由于协同作用,AG-GO复合材料抑制了测试细菌的生长和繁殖,大肠杆菌和耐甲氧西林的金黄色葡萄球菌在最初的2小时内抑制了金黄色葡萄球菌的生长和繁殖,然后在24小时内完全停止其生长。发现用人角膜上皮细胞测试的Ag-Go剂量的细胞活力为85%,这表明复合材料的无毒行为。此外,Ag-Go纳米复合材料Exibits增强了有毒有机染料的光催化降解特性。该复合材料显示了24分钟内若丹明B的降解,在14分钟内,甲基蓝的97%和12分钟内的99%的商用染料降解。发现光催化效率比纯GO高约五倍。在光催化过程中,通过Ag纳米颗粒的表面等离子体共振产生的活性氧(ROS)负责良好的细菌种群控制以及增强的光催化降解活性。 Ag-Go纳米复合材料的可重复使用性和可回收性表明其具有结构稳定性和良好生物相容性的商业利用。

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