Two 3D Copper(II/I) Coordination Polymers: Structures, Energetic and Magnetic Properties

摘要

Two copper compounds, [CuII 4(OH)0.5 (MTZ)2(N3)5.5(H2O)0.5]n (1) and [CuI (MTZ)]n?0.17n(H2O) (2), [MTZ (5-methyl tetrazolate) is generated by in situ hydro/solvothermal reaction], were pre- pared. Compound 1 shows a 3D structure with ((82 ?10) metal topology and exhibits antiferromagnetic interactions through the complicated EO-N3, μ2-OH and μ-N,N-tetrazolate bridges. Compound 2 also displays a 3D structure with (83 ) metal topology, which shows good thermal stability and potential high-energetic properties.