Potassium Iodide as a New Nucleophilic Catalyst for the Novel Synthesis of Ionic Vinyl Compounds: Experimental and Theoretical Kinetic Approaches

摘要

In this work,for the first time,we introduce potassium iodide as a green,inexpensive,and widely available nucleophilic catalyst for the successful synthesis of an ionic vinyl compound.FT-IR,~1HNMR,~(13)CNMR,energy-dispersive spectroscopy(EDS),C,H,N elemental analysis and mass spectroscopy were used for the product characterization.The reaction mechanism investigated experimentally employing the UV-vis method and theoretically at the M06-2x/6-31+G(d,p)-dgdzvp levels of theory.Pure water and step5-in which vinylic bond appears-were kinetically recognized as the best solvent and R.D.S,respectively.