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Assembly of SBA-15 Derived Hybrid Heterogeneous Catalysts for Liquid Phase Cyclopentene Epoxidation

机译:SBA-15衍生的混合异质催化剂的组装,用于液相环烯环氧化

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摘要

Three two-dimensional SBA-15-based hybrid materials, SBA-15- ImCl-PF6, SBA-15-NH(PO3H2), and SBA-15-N+, were synthesized employing a post-synthetic functionalization strategy, and peroxo-W and PW species were successfully immobilized on the surface of the corresponding organic moieties-modified SBA-15 via electrostatic interaction or covalent linking. The TEM and XRD results presented that the structure and morphology of SBA-15 were maintained after multiple transformations.
机译:三种二维基于SBA-15的混合材料,SBA-15- IMCL-PF6,SBA-15-NH(PO3H2)和SBA-15-N+,采用后合成功能化策略和Peroxo-W-W-W 通过静电相互作用或共价链接,成功地将PW物种成功固定在相应的有机部分修饰的SBA-15的表面上。 TEM和XRD结果表明,在多次转化后保持了SBA-15的结构和形态。

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