One-Pot Selective Synthesis of Renewable p-Xylene by Completely Biomass-Based Ethanol and Dimethylfuran with Functionalized Mesoporous MCM-41

摘要

One-pot direct synthesis of renewable p-xylene (PX) via Diels- Alder cycloaddition of completely bio-based ethanol and 2,5- dimethylfuran (DMF) was studied comparatively over deal- uminated HBeta zeolite and functionalized mesoporous MCM- 41. The sulfonic group-functionalized MCM-41 had better catalytic performances. Under the optimized conditions, an ethanol conversion of ~100%, 2,5-DMF conversion of 79% and PX selectivity of 80% were obtained over NH3-Silylated-MCM- 41-10%SO3H catalyst with 0.8 wt% N content, which is much better than HBeta zeolite catalyst. X-ray diffraction (XRD), thermogravimetric analysis (TGA), 29 Si cross-polarization magic- angle spinning (CP/MAS) NMR and infared (IR) characterizations showed that sulfonic and silylated groups have been success- fully grafted onto MCM-41. Quantitative 1 H MAS NMR with d5- pyridine adsorption unambiguously demonstrated that sily- lated MCM-41-SO3H with NH3 pre-treatment has much higher amount and stronger strength of Bronsted acid than zeolite catalyst. This is the vital factor to catalyze the dehydration of ethanol to ethylene and speed up the Diels-Alder cycloaddition reaction, ultimately increase PX selectivity and reduce much less soft-coke deposit on MCM-41-SO3H (~4 wt%) than on HBeta zeolite (~12 wt%). This work demonstrates a simple and economical strategy to further improve the potential for the production of sustainable chemicals from complete biomass.