A new class of Dy-III-SIMs associated with a guanidine-based ligand

摘要

A family of four mononuclear Dy-III complexes of the guanidine-based ligand L [L = tris(2-hydroxybenzylidene)triaminoguanidine] with formulas [DyLCl2(DMF)(2)]center dot DMF center dot CH3OH (1), [DyL2(CH3OH)(2)]Br center dot H2O center dot 3CH(3)OH (2), [DyL2(H2O)(2)]SCN center dot 3H(2)O center dot CH3OH (3) and [DyL2(CH3OH)(2)]SCN center dot CH3CN center dot CH3OH (4) were successfully prepared by varying reaction conditions. Complex 1 is seven-coordinate, with three N2O from ligand L along with two equatorially trapped DMF molecules and two axial Cl- anions, adopting pentagonal bipyramidal D-5h symmetry. Complexes 2-4 have somewhat similar structures with six donor N4O2 sites from two ligands and two O from corresponding solvent molecules, featuring a N4O4 octa-coordinate environment with triangular dodecahedron D-2d symmetry. Magnetic investigations indicated that complex 1 did not demonstrate single-molecule magnetic behavior, while complexes 2-4 were single-ion magnets (SIMs) under zero applied DC field with the effective energy barriers (U-eff) of 207.3 (2), 222.5 (3) and 311.7 K (4), respectively. The different types of coordinated solvent molecules and counter anions caused changes in intermolecular interactions and coordination geometries that severely affected their magnetic dynamics. The magnetic behaviors of these complexes were investigated through complete-active space self-consistent field (CASSCF) calculations with the inclusion of spin-orbit effects. Calculations revealed that the measured differences in magnetic behaviors originated mainly from intermolecular and crystal-packing effects as isolated complexes 1-4 have almost identical electronic and magnetic properties.