Structural elucidation and dielectric behavior evaluation of Dy-Ni substituted manganese ferrites

摘要

Dy-Ni substituted Mn1-xNixFe2-yDyyO4 (x = 0.0-0.1 and y = 0.0-0.2) soft magnetic oxides were synthesized using a size controlled micro-emulsion method. X-ray diffraction (XRD) analysis was employed to confirm the spinel structure of synthesized ferrites. Crystallite size was found to decrease (33-22 nm) while lattice constant was increased (8.58-8.63 angstrom) by increasing dopants content. FTIR bands observed in the range 500-600 cm(-1) is the evidence to form the spinel structure of these ferrites. Dielectric constant (epsilon') and dielectric loss (epsilon '') were observed to decrease with the increase of frequency due to hopping mechanism. Hysteresis curves exhibited soft nature of synthesized nanoferrites. Remanence (M-R) and saturation magnetization (M-S) were increased with the incorporation of Dy and Ni ions. The decreased in dielectric losses and increased in magnetic parameters suggested that these ferrites are potential candidates for magnetic recording heads.