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Magnetically responsive polymer nanopillars with nickel cap

机译:磁性响应性聚合物纳米粒子与镍帽

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摘要

Embedding magnetic particles within polymer matrix is a common and facile method to fabricate magnetically responsive micro-/nanoscale pillars. However, the balance between mechanical compliance and magnetic susceptibility cannot be decoupled and the particles are limited by the pillar feature size, which can limit the actuation performance. Here we demonstrate a new type of magnetically responsive nanostructure consisting of a polydimethylsiloxane (PDMS) nanopillar array with deposited nickel caps, that has successfully achieved such decoupling with multiple cap-geometry designs for a better actuation control. The actuation result of nanopillars with 540 nm period and 1.3 mu m height has been analyzed using image processing, leading to a maximum displacement of 180 nm with a ratio of 13.9% with respect to the pillar height. Magnetic and mechanical models based on magnetic force and torque have been developed and used to mitigate the weakening effect of the actuation by the residual magnetic layer. This structure demonstrates a feasible strategy for magnetic actuation at the sub-micrometer scale with freedom to design magnetic cap and polymeric pillar separately. This structure can also be utilized in multiple applications such as tunable optical elements, dynamic droplet manipulation, and responsive particle manipulation.
机译:在聚合物基体中嵌入磁性颗粒是制备磁响应微/纳米柱的一种常见且简便的方法。然而,机械柔度和磁化率之间的平衡无法解耦,颗粒受柱特征尺寸的限制,这可能会限制驱动性能。在这里,我们展示了一种新型的磁响应纳米结构,该结构由聚二甲基硅氧烷(PDMS)纳米柱阵列和沉积的镍帽组成,它成功地实现了与多帽几何形状设计的去耦,以实现更好的驱动控制。利用图像处理技术对周期为540nm、高度为1.3μm的纳米柱的驱动结果进行了分析,导致最大位移为180nm,与柱高度的比率为13.9%。基于磁力和转矩的磁性和机械模型已经开发出来,并用于减轻残余磁层驱动的削弱效应。这种结构展示了一种可行的亚微米级磁驱动策略,可以自由地分别设计磁帽和聚合物柱。该结构还可用于多种应用,如可调谐光学元件、动态液滴操纵和响应性粒子操纵。

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