Electrolysis-enhanced ecological floating bed and its factors influencing nitrogen and phosphorus removal in simulated hyper-eutrophic water

摘要

To enhance ammonia nitrogen (NH3-N) and phosphate (PO43--P) removal in hyper-eutrophic water, electrolysis-enhanced ecological floating bed (EEEFB) was designed with a Mg-Al alloy anode, a Ir-Ta-Ti metal oxide-coated titanium anode, and an Fe anode with the same graphite cathode. The results showed that the Mg-Al alloy anode with graphite cathode had a better ability to enhance NH3-N and PO43--P removal. When the current density was 0.37 mA.cm(-2), the electrolysis time was 24 h/d, and the net removal rates of NH3-N and PO43--P were 62% and 99.4%, respectively. In winter, the purification efficiencies of NH3-N and PO43--P were as high as 7388.4 mg.m(-2) and 4297.5 mg.m(-2), respectively, by EEEFBs which were significantly higher than the traditional ecological floating bed (p < 0.05). Scanning electron microscopy (SEM) and X-ray spectrometry confirmed that the PO43--P was deposited in the sediment of EEEFBs with Mg-Al alloy anode and Fe anode.