A novel route to superhard nanocrystalline cubic boron nitride: Emulsion detonation and high-pressure high-temperature transformation-assisted consolidation

摘要

Synthesizing bulk nanocrystalline materials is challenging since grain growth should be suppressed whereas densification promoted. Here, we demonstrate a novel route to synthesize superhard bulk nanocrystalline cubic boron nitride (cBN), which combines the use of emulsion detonation and high-pressure high-temperature transformation-assisted consolidation. The emulsion detonation process activates BN to possess unique structure and chemistry, i.e. wurtzitic BN nanograins in hexagonal BN matrix with enhanced structural disordering and oxygen impurity, a combination that enhances the nucleation rate of cBN and its densification leading to the formation of bulk nanocrystalline cBN at reduced conditions. The cBN, synthesized at 7.5 GPa and 1800 C, displayed Vickers hardness values of 50-62 GPa for 5-20 N loads. The findings in the study suggest a feasible solution to synthesize bulk nanocrystalline cBN in a more scalable way, while also providing design insights on how to refine grain growth while enhancing densification to synthesize bulk nanocrystalline materials.