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Studies on natural rubber nanocomposites by incorporating zinc oxide modified graphene oxide

机译:掺入氧化锌改性石墨烯氧化物的天然橡胶纳米复合材料

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To obtain an efficient performance of the natural rubber/graphene oxide nanocomposites, it is essential to enhance the interfacial interaction between the filler and the polymeric matrix. The present study aims to improve the interfacial interaction between natural rubber (NR) and graphene oxide (GO) by modifying GO with zinc oxide nanoparticles (ZGO) using the coprecipitation method. The structural and morphological properties of ZGO nanocomposites were characterised by using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Raman spectroscopy, UV-visible spectrophotometry (UV-vis), Transmission electron microscopy (TEM) and Scanning electron microscopy (SEM). The characterisation results show that zinc oxide (ZnO) nanoparticles were synthesised and randomly decorated on the surfaces and edges of GO sheets. A series of NR-ZGO nanocomposites with varying compositions of ZGO were prepared by the latex mixing method. The morphological, mechanical, and dielectric properties of the nanocomposites were analysed by SEM, UTM, and impedance analyser. The results obtained for NR-ZGO nanocomposites revealed enhancement in mechanical and dielectric properties from neat NR and NR-GO nanocomposites.
机译:为了获得高效的天然橡胶/氧化石墨烯纳米复合材料,必须增强填料与聚合物基体之间的界面相互作用。本研究旨在通过共沉淀法用氧化锌纳米颗粒(ZGO)修饰氧化石墨烯(GO),改善天然橡胶(NR)与氧化石墨烯(GO)之间的界面相互作用。采用傅里叶变换红外光谱(FTIR)、X射线衍射(XRD)、拉曼光谱、紫外可见分光光度法(UV-vis)、透射电子显微镜(TEM)和扫描电子显微镜(SEM)对ZGO纳米复合材料的结构和形貌进行了表征。表征结果表明,氧化锌(ZnO)纳米颗粒被合成并随机修饰在GO板的表面和边缘。采用乳液共混法制备了一系列不同ZGO组成的NR-ZGO纳米复合材料。通过SEM、UTM和阻抗分析仪分析了纳米复合材料的形态、力学和介电性能。NR-ZGO纳米复合材料的结果表明,纯NR和NR-GO纳米复合材料的机械和介电性能有所提高。

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