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In-situ formation of Zn oxide particles in CuZn matrix during friction stir processing

机译:摩擦搅拌加工过程中Cuzn基质中Zn氧化物颗粒的原位形成

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摘要

Cu-30Zn plates were friction stir processed at a rotational speed of 1120 rpm and a traverse speed of 50 mm/min. Two kinds of samples were produced. The first sample was friction stir processed without using a secondary phase. In the case of the second sample, Al(2)O(3)particles were incorporated into the Cu-30Zn plates to produce a surface nanocomposite. In the absence of Al(2)O(3)particles, the produced sample showed the typical microstructures of friction stir processed brass alloys. However, in the presence of Al(2)O(3)particles, the SZ showed a bimodal grain structure, and Zn oxide particles were formed. The high heat input condition of FSP caused the evaporation and scape of Zn from the CuZn matrix. The evaporated Zn reacted with oxygen of the air entrapped between the Al(2)O(3)particles, which formedin-situand encapsulated Zn oxide particles. This phenomenon has not been yet reported in the literature.
机译:在转速为1120 rpm、横向速度为50 mm/min的条件下,对Cu-30Zn板材进行搅拌摩擦加工,制备了两种试样。第一个样品在不使用第二相的情况下进行搅拌摩擦处理。在第二个样品的情况下,Al(2)O(3)颗粒被加入到Cu-30Zn板中以产生表面纳米复合材料。在没有Al(2)O(3)颗粒的情况下,制备的样品显示了搅拌摩擦加工黄铜合金的典型微观结构。然而,在Al(2)O(3)颗粒的存在下,SZ呈现双峰晶粒结构,并形成Zn氧化物颗粒。FSP的高热输入条件导致锌从CuZn基体中蒸发和脱落。蒸发的锌与夹在Al(2)O(3)颗粒之间的空气中的氧气发生反应,形成原位和包裹的氧化锌颗粒。这一现象尚未在文献中报道。

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