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Improving hot corrosion resistance of Cr3C2-20NiCr coatings with CNT reinforcements

机译:用CNT增强剂提高CR3C2-20NICR涂层的热腐蚀性

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摘要

Carbon Nanotubes (CNT) reinforced Cr3C2-20NiCr composite coatings were prepared and deposited on alloy steel using high-velocity oxyfuel (HVOF) thermal spraying method. The comparative effects of variation in CNT content (from 1 to 2 weight percentage) on mechanical properties and hot corrosion behaviour in super-heater zone of actual coal-fired boiler of a thermal power plant at 900 degrees C have been investigated. After exposure to boiler environment, the corrosion products have been analysed by thermogravimetric analysis, X-ray diffraction, scanning electron microscopy, energy dispersive and cross-sectional analysis techniques. The results confirmed that variation in CNT content improved the mechanical and microstructural properties of surface coatings by modifying their surface characteristics. The variation in CNT content improved the corrosion protection property of composite coating at high temperature of exposure. Reduction in corrosion rate was observed with increase in CNT content from 1 to 2 weight percentage in the Cr3C2-20NiCr coating matrix.
机译:采用高速氧燃料(HVOF)热喷涂方法在合金钢表面制备了碳纳米管(CNT)增强Cr3C2-20NiCr复合涂层。研究了900℃时,碳纳米管含量(1~2重量百分比)变化对火力发电厂实际燃煤锅炉过热器区机械性能和热腐蚀行为的比较影响。暴露于锅炉环境后,通过热重分析、X射线衍射、扫描电子显微镜、能量色散和横截面分析技术对腐蚀产物进行了分析。结果证实,碳纳米管含量的变化通过改变表面特性改善了表面涂层的机械和微观结构性能。碳纳米管含量的变化改善了复合涂层在高温下的防腐性能。在Cr3C2-20NiCr涂层基体中,随着CNT含量从1重量百分比增加到2重量百分比,腐蚀速率降低。

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