<![CDATA[The standard enthalpy of formation of superionic solid electrolyte Li <ce:inf loc='post'>7</ce:inf>La <ce:inf loc='post'>3</ce:inf>Zr <ce:inf loc='post'>2</ce:inf>O <ce:inf loc='post'>12</ce:inf>]]>

E.A. Il’ina; A.A. Raskovalov; A.P. Safronov

首页> 外文期刊>Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems >7La 3Zr 2O 12]]>

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7La 3Zr 2O 12]]>

机译：<！[CDATA [固体形成标准焓固体电解质Li 7 在 3 ZR 2 O 12 ]]>

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?The measured enthalpy of Li7La3Zr2O12dissolution in 1M HCl is equal to ?1816.0Jg?1.

?The enthalpy of LLZ formation from binary oxides is equal to ?168.0kJmol?1.

?The standard enthalpy of LLZ formation from elements is equal to ?7152.6kJmol?1.

Abstract

The standard enthalpy of formation of perspective solid electrolyte Li7La3Zr2O12is determined using thermodynamic cycles based on the measurement of its enthalpy of dissolution. The standard molar enthalpies of dissolution in aqueous solution of 1moldm?3HCl, formation from binary oxides and formation from elements for tetragonal form of Li7La3Zr2

机译：highlights

测得的锂热“>3Zr2O12在1M HCl中的溶解等于？1816.0Jg1二元氧化物形成LLZ的焓等于？168.0kol1？元素形成LLZ的标准焓等于7152.6kJmol<1摘要透视固体电解质锂的标准生成焓“>12是根据溶解焓的测量，通过热力学循环确定的。1moldm3HCl水溶液中的标准摩尔溶解焓，由二元氧化物形成，以及由元素形成四方形式的Li7La3Zr2

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来源
《Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems》 |2017年第2017期|共5页
作者
E.A. Il’ina; A.A. Raskovalov; A.P. Safronov;
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作者单位

Institute of High-Temperature Electrochemistry of Ural Branch of RAS;

Institute of High-Temperature Electrochemistry of Ural Branch of RAS;

Ural Federal University named after the first President of Russia B.N. Yeltsin.;

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原文格式 PDF
正文语种 eng
中图分类其他物理及物理化学分析法;热化学;
关键词
Li7La3Zr2O12; Solid electrolyte; Solution calorimetry; Enthalpies of dissolution; Enthalpies of formation;

机译：Li7la3zR2O12;固体电解质;溶液量热法;溶解焓;形成的焓;

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7La 3Zr 2O 12]]>

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