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Effect of micro- and nanofiller hybrids on the dynamic mechanical properties of glass reinforced epoxy composites

机译:微型和纳米筛选杂种对玻璃增强环氧复合材料动态力学性能的影响

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Reinforcement of epoxy glass fabric composites with nano- and micro-fillers has resulted in the development of polymer composites with good electrical, thermal, and mechanical properties. The present work attempts to estimate the impact of hybrid fillers on dynamic-mechanical properties of the epoxy composites with a different filler. The dynamic mechanical parameters such as storage modulus, loss modulus, and damping factor over a temperature of 25 degrees C-250 degrees C have been investigated. The viscoelastic properties of composites are also confirmed with a Cole-Cole plot. From the results, the storage modulus of the composites is observed to lie in the range of 8000 to 12,500 MPa, and the epoxy composite with silicon carbide filler shows the highest storage modulus. Composite with 5 wt% of alumina shows the maximum loss modulus of 2100 MPa. The glass transition temperature of the base epoxy composite is 135 degrees C and it increases to 137 degrees C with the incorporation of hybrid cenosphere and molybdenum sulfide fillers. The storage modulus shows only marginal differences as compared to their counterparts with nanofillers but is higher by about 10-15% in comparison to the micron filler-based composites. However, the differences in the loss modulus of the nanocomposites, hybrid composites, and the composites with micron-sized filler are not significant.
机译:用纳米和微米填料增强环氧玻璃纤维织物复合材料导致了具有良好电、热和机械性能的聚合物复合材料的发展。本研究试图评估杂化填料对不同填料的环氧复合材料动态力学性能的影响。研究了25℃-250℃温度下的动态力学参数,如储能模量、损耗模量和阻尼系数。复合材料的粘弹性性能也通过科尔-科尔曲线图得到了证实。结果表明,复合材料的储能模量在8000~12500mpa之间,含碳化硅填料的环氧复合材料的储能模量最高。含有5 wt%氧化铝的复合材料的最大损耗模量为2100 MPa。环氧树脂基复合材料的玻璃化转变温度为135℃,加入杂化空心微珠和硫化钼填料后,玻璃化转变温度增加到137℃。与纳米填料相比,储能模量仅略有差异,但与微米填料基复合材料相比,储能模量高出约10-15%。然而,纳米复合材料、杂化复合材料和含有微米级填料的复合材料的损耗模量差异不显著。

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