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首页> 外文期刊>Journal of Molecular Liquids >Comments on 'Stearic acid solubility in mixed solvents of (water plus ethanol) and (ethanol plus ethyl acetate): Experimental data and comparison among different thermodynamic models'
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Comments on 'Stearic acid solubility in mixed solvents of (water plus ethanol) and (ethanol plus ethyl acetate): Experimental data and comparison among different thermodynamic models'

机译:评注“(水加乙醇)和(乙醇加乙酸乙酯)和(乙醇加乙酸乙酯)的”硬脂酸溶解度“:不同热力学模型的实验数据和比较”

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摘要

A polemic is given regarding the author's calculated values pertaining to the "goodness-of-fit" used to indicate the better of the predictive expressions considered to describe the observed solubility data of stearic acid. In the case of the van't Hoff model the author averaged the individual relative deviations for the solubility of stearic acid in both the ethanol and ethyl acetate mono-solvents. Positive and negative relative individual deviations would thus cancel. For the modified Apelblat model the author averaged the absolute values of the individual relative deviations for the solubility of stearic acid in the two organic mono-solvents. (C) 2020 Elsevier B.V. All rights reserved.
机译:本文就作者计算的硬脂酸溶解度数据的“拟合优度”的值进行了讨论,该值用于表明用于描述硬脂酸的观察溶解度数据的预测表达式是否更好。在范特霍夫模型的情况下,作者平均了硬脂酸在乙醇和乙酸乙酯单溶剂中溶解度的单个相对偏差。因此,正的和负的相对个体偏差将被抵消。对于改进的Apelblat模型,作者平均了硬脂酸在两种有机单溶剂中溶解度的各个相对偏差的绝对值。(C) 2020爱思唯尔B.V.版权所有。

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