APPLICATION OF LYOCELL FIBER STRUCTURE FORMATION MECHANISM IN FLAME-RETARDANT MODIFICATION OF LYOCELL FIBER

摘要

In order to overcome the disadvantage of Lyocell fiber flammability, two types of flame-retardant finishing liquids, 2-carboxyethyl phenylphosphic acid (CEPPA) and N-hydroxymethyl-3-dimethoxyphosphoacyl propanamide (MDPA), were used in this study to treat Lyocell fiber in two different states: never-dried and dry. The results showed that CEPPA and MDPA can react with the hydroxyl groups of the cellulose and graft onto the Lyocell fiber under appropriate conditions, resulting in increased flame-retardant performance of the fiber, a slight reduction in crystallinity, and a significant decline in mechanical properties. Compared with the dry fiber, the P content and LOI of the fiber obtained by treating the as-spun never-dried Lyocell fiber rose significantly: the P content was higher by 38.9% (for CEPPA) and 20.5% (for MDPA), respectively, while the LOI increased by 6.0% (for CPPA) and 4.0% (for MDPA), respectively, which means that the fiber had better flame-retardant performance. Although the breaking strength of the fiber decreased, it still met the requirements for textiles. In addition, direct flame-retardant treatment of never-dried wet fiber can reduce energy consumption by avoiding repeated drying. Furthermore, the results of this study also have guiding significance for other post-processing procedures for Lyocell fibers, such as dyeing, catalyst infiltration during carbon fiber preparation etc.