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Efficient recovery of the dyed cotton-polyester fabric: cellulose nanocrystal extraction and its application in composite films

机译:染色棉涤纶织物的有效回收:纤维素纳米晶萃取及其在复合薄膜中的应用

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摘要

Herein, cotton fiber and polyester fiber were separated from their blended fabric by a dilute acid pretreatment combined mechanical grinding process with a total recovery rate of 92.1 %. The recovered cotton fiber was bleached and used to extract cellulose nanocrystals (CNCs). Compared with those extracted from the never-used cotton fibers, the resultant CNCs are lower in aspect ratio, higher in aqueous transparency and better in dispersion stability. Furthermore, the as-prepared CNCs, together with silica nanoparticles, were employed as the reinforcements to fabricate films with methylcellulose. The addition of the nanofillers endowed the pure methylcellulose films with a 200% improvement in tensile strength while slightly affected the transparency of the films. High-efficient recovering of dyed natural/synthetic fiber blended textiles, high-quality CNC extraction, and high-performance composite film fabrication achieved in this work is conducive to the utilization of waste resources and the saving of primary resources. Graphic abstract
机译:采用稀酸预处理与机械研磨相结合的方法,将棉纤维和涤纶纤维从混纺织物中分离出来,总回收率为92.1%。将回收的棉纤维漂白并用于提取纤维素纳米晶体(CNC)。与从未使用过的棉纤维相比,所得CNC的长径比更低,水透明度更高,分散稳定性更好。此外,将所制备的CNC与二氧化硅纳米颗粒一起用作增强材料,以制备甲基纤维素薄膜。纳米填料的加入使纯甲基纤维素薄膜的拉伸强度提高了200%,但对薄膜的透明度影响不大。本工作实现了染色天然纤维/合成纤维混纺织物的高效回收、高质量CNC萃取和高性能复合膜制作,有利于废弃物资源的利用和一次资源的节约。图形摘要

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