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ОСОБЕННОСТИ ПЕРЕКРИСТАЛЛИЗАЦИИ ПАНДЕРМИТА В ГИДРОТЕРМАЛЬНЫХ УСЛОВИЯХ

机译:水热条件下鲍兹州的重结晶特征

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摘要

Borate minerals often have the polycrystalline nature, so it seems to be useful determining conditions of their synthesis, with recovering of their monocrystalline specimens, by the way to study the structure of those minerals. Hydrothermal synthesis is quite purposeful for modeling the natural borate mineralization within exogenic systems. This paper displays results of the pandermite recrystallization at hydrothermal conditions under +260 deg C and 20 bar pressure. The obtained crystals were investigated by X-ray analysis and IR-spectroscopy. Identification of the powder pattern has shown the close similarity of studied specimen to the natural Ca-borate - korzhinskite. Contrary to korzhinslcite, the IR spectrum didn't prove the presence of H_2O molecules in the synthesized compound. So, it should be assumed that the obtained compound is intermediate member between korzhinskite and calciborite, CaB_2O_4.
机译:硼酸矿物通常具有多晶的性质,因此似乎有用的确定它们的合成条件,通过研究这些矿物的结构的方式回收它们的单晶试样。 水热合成对于建模外生系统内的天然硼酸盐矿化是非常有目的的。 本文显示了在+ 260℃和20巴压下的水热条件下的Pandermite重结晶的结果。 通过X射线分析和IR光谱研究得到的晶体。 粉末图案的鉴定表明,研究标本对天然CA-硼酸盐 - Korzhinskite的近似相似性。 与Korzhinslcite相反,IR光谱没有证明合成化合物中的H_2O分子的存在。 因此,应该假设所得化合物是Korzhinskite和Calciborite之间的中间构件,Cab_2O_4。

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