The suppression of space charge accumulation in CB/LDPE nanocomposites and its association with molecule relaxation

摘要

Space charge accumulation within insulating material poses a threat to the reliability in the operation of DC power cables. To investigate the influence of carbon black (CB) on the space charge accumulation of low density polyethylene (LDPE), both conductive carbon black (C-CB) and insulating carbon black (I-CB) were employed as filler particles. The space charge distributions of LDPE and CB/LDPE nanocomposites were obtained by the pulsed electro-acoustic (PEA) method. Additionally, dynamic mechanical analysis (DMA) and thermally stimulated current (TSC) spectroscopy were applied to explore the mechanism of improving space charge performance. Both the C-CB/LDPE and I-CB/LDPE nanocomposites can effectively suppress space charge accumulation. It was concluded that the improvement in space charge characteristics of CB/LDPE nanocomposites was attributable to the interaction between the CB particles and the LDPE, which reduces the number of defects formed from molecules participating in α relaxation and decreases the density of traps within the LDPE.