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Temperature-dependent transport properties of a FeTe compound

机译:粉末化合物的温度依赖性运输性能

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Temperature-dependent transport properties of a FeTe parent compound have been investigated by measurements of electrical resistivity p(T), thermal conductivity k(T) and Seebeck coefficient S(T). The sample was synthesized using a standard solid state reaction route via vacuum encapsulation and characterized by X-ray diffraction spectroscopy, which indicated a tetragonal phase with the space group PA/nmm. The resistivity measurement data of the parent FeTe compound do not exhibit superconductivity however, it shows an anomaly in the temperature-dependent resistivity at around 67 K, which corresponds to structural phase transition in the vicinity of a magnetic phase transition. In the low temperature regime, Seebeck coefficient, S(T), exhibited an anomalous dip feature and negative throughout the temperature range, indicating an electron-like, single band charge carrier mechanism. We have also estimated the power factor and thermoelectric figure of merit ZT, which is found to be significantly smaller than other compositions of iron chalcogenides.
机译:通过测量电阻率P(t),导热率k(t)和塞贝克系数S(t)研究了粉末母体化合物的温度依赖性运输性能。使用标准固态反应路径通过真空包封合成样品,并通过X射线衍射光谱表征,其用空间组PA / NMM表示四边形相。母弓型化合物的电阻率测量数据不具有超导电性,但是它显示出在约67k的温度依赖性电阻率的异常,其对应于磁相转变附近的结构相转变。在低温调节条件下,Seebeck系数,S(t),在整个温度范围内呈现异常浸渍特征和负,表示电子样的单带电荷载体机构。我们还估计了功率因数和优选ZT的热电值,发现该功率因数和热电值是明显小于其他铁硫芥子的组成。

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