首页> 外文期刊>The journal of physical chemistry, C. Nanomaterials and interfaces >Effect of Nanochannel Diameter and Debye Length on Ion Current Rectification in a Fluidic Bipolar Diode
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Effect of Nanochannel Diameter and Debye Length on Ion Current Rectification in a Fluidic Bipolar Diode

机译:纳米通道直径和德拜长度对流体双极二极管中离子电流整流的影响

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摘要

We have simulated ion current rectification (ICR) in a bipolar nanochannel fluidic diode for different nanochannel diameters, electrolyte concentrations, and surface charge densities. The ICR decreases with diameter of the fluidic nanochannel due to decrease in unipolar character of the electrolyte, The ICR decreases with electrolyte concentration due to surface charge screening by counterions. The ICR increases with channel diameter for a given ratio of channel diameter to Debye length. Scaling of forward and reverse current densities with electrolyte concentration has been determined using curve fitting for different values of surface charge densities and channel diameters. The ICR can be increased by increasing surface charge density to enhance unipolar character of the electrolyte. The fluid velocity close to the nanochannel walls is driven by body force and along the center by the fluid pressure, which gives rise to a curly fluid flow.
机译:我们已经在双极性纳米通道流体二极管中模拟了离子电流整流(ICR),以适应不同的纳米通道直径,电解质浓度和表面电荷密度。由于电解质的单极特性降低,ICR随着流体纳米通道直径的增加而降低;由于抗衡离子对表面电荷的筛选,ICR随着电解质浓度的降低而降低。对于给定的通道直径与德拜长度之比,ICR随通道直径而增加。对于不同的表面电荷密度和通道直径,已使用曲线拟合确定了正向和反向电流密度与电解质浓度的比例关系。可以通过增加表面电荷密度来增加ICR,以增强电解质的单极性特性。靠近纳米通道壁的流体速度是由体力驱动的,并且是由流体压力沿中心驱动的,这导致了卷曲的流体流动。

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