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Condensation transition in polydisperse hard rods

机译:多分散硬棒中的冷凝转变

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We study a mass transport model, where spherical particles diffusing on a ring can stochasticallyexchange volume v, with the constraint of a fixed total volume V=Σ_(i=1)~Nv_i,Nbeing the total number of particles. The particles, referred to as p-spheres, have a linear size that behaves as v_i~(1/p)and ourmodel thus represents a gas of polydisperse hard rods with variable diameters v_i~(1/p).We show that our model admits a factorized steady state distribution which provides the size distribution that minimizes the free energy of a polydisperse hard-rod system, under the constraints of fixed N andV. Complementary approaches (explicit construction of the steady state distribution on the one hand;density functional theory on the other hand) completely and consistently specify the behavior of the system. A real space condensation transition is shown to take place for p> 1; beyond a critical density a macroscopic aggregate is formed and coexists with a critical fluid phase. Our workestablishes the bridge between stochastic mass transport approaches and the optimal polydispersity of hard sphere fluids studied in previous articles.
机译:我们研究了一种传质模型,其中在环上扩散的球形粒子可以随机交换体积v,总体积V =Σ_(i = 1)〜Nv_i固定为N,即粒子总数。称为p球的粒子具有线性大小,其行为为v_i〜(1 / p),因此我们的模型代表了直径为v_i〜(1 / p)的多分散硬棒气体。允许在固定N和V的约束下提供因数分解的稳态分布,该分布提供了使多分散硬棒系统的自由能最小化的尺寸分布。互补方法(一方面是明确构造稳态分布;另一方面是密度泛函理论)完全一致地指定了系统的行为。 p> 1时发生实空间凝结转变;超过临界密度,会形成宏观聚集体,并与临界液相共存。我们的工作为随机传质方法与硬球流体的最佳多分散性之间建立了桥梁。

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