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Columnar versus smectic order In systems of charged colloidal rods

机译:柱状与近晶顺序在带电胶体棒系统中

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We study the stability of inhomogeneous liquid crystalline states in systems of monodisperse,stiff,charged rods.By means of a bifurcation analysis applied to the Onsager free energy for charged rods in strongly nematic states,we investigate nematic-smectic and nematic-columnar instabilities as a function of the Debye screening length kappa-1.While the nematic-smectic transition clearly preempts the nematic-columnar one in the regime of strong screening (i.e.,small kappa~(-1)) a marked stability of hexagonal columnar order is observed at larger screening lengths.The theoretical results are substantiated by Brownian dynamics computer simulation results based on the Yukawa site model.Our findings connect to experiments on tobacco mosaic virus rods,in particular,but might be relevant for soft rodlike mesogens in strong external directional fields in general.
机译:我们研究了单分散,刚性,带电棒系统中非均质液晶态的稳定性。通过将分叉分析应用于强向列态带电棒的Onsager自由能,我们研究了向列-电和列向列不稳定性。在强筛选(即小kappa〜(-1))模式下,向列相-近晶相转变明显优先于向列相-柱状相,但观察到六方柱状有明显的稳定性理论结果被基于Yukawa站点模型的布朗动力学计算机仿真结果所证实。我们的发现尤其与烟草花叶病毒棒的实验有关,但可能与强外部定向场中的软棒状介晶有关一般来说。

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