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Impurity-stimulated heterogeneous nucleation of supercooled H_2 clusters

机译:过冷的H_2团簇的杂质刺激异质成核

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摘要

The sizes and mass spectra of large (N=1900-13 700 molecules) cold (approx3.1K) H_2 clusters have been measured after scattering from CO molecules.Cluster-size measurements after between 2 and 8 collisions indicate that 7% of the H_2 molecules are evaporated.This loss agrees with calculations for the numer of H_2 molecules evaporated by the heat released in the transition from an initial liquid state to a final solid state.Event hough heterogeneous nucleation is initiated after only a few collision with CO molecules,the mass spectr show that additional captured CO molecules coagulate to form large CO clusters with up to n=11 molecules,suggesting that the outer layer is sufficiently liquidlike to facilitate mobility of the CO molecules.Since the calculated H_w cluster temperature (approx3.1K) is below the superfluid transition temeprature predicted for pH_2 with density between 40% and 80% of the triple-point density,a shell-like region of low density near the cluster surface can be expected to the superfluid.
机译:从CO分子散射后,测量了大(N = 1900-13 700分子)冷(约3.1K)H_2团簇的大小和质谱图。2至8次碰撞后的簇大小测量表明7%的H_2这种损失与从初始液态到最终固态的转变过程中释放的热量所蒸发的H_2分子的数量的计算结果相符。仅在与CO分子发生几次碰撞后,异质成核才开始发生。质谱表明,捕获的额外CO分子凝结形成多达n = 11个分子的大CO簇,这表明外层具有足够的液体状,可促进CO分子的迁移。因为计算出的H_w簇温度(约3.1K)为低于pH_2预测的超流体转变温度,密度在三点密度的40%到80%之间,可以在簇表面附近形成一个低密度的壳状区域对超流体。

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