High-pressure spectroscopic probe of hydrophobic hydration of the methyl groups in dimethyl sulfoxide

摘要

The hydrophobic hydration of dimethylsulfoxide (DMSO)/D_2O was explored using a combination of the high-pressure method and ab initio calculations. The frequencies of the C-H stretching vibration of DMSO increase as the mole fraction of D_2O increases, while no appreciable changes in spectral shapes are observed upon dilution. Interestingly, the infrared spectra of DMOS/D_2O observed shapes are observed upon dilution. Interestingly, the infrared spectra of DMSO/D_2O observed under high-pressure exhibits dramatic changes, while the new spectral features locating at approx 2942 and approx 3033 cm~(-1) appear. The spectral changes were attributed to the combined effect of C-H-O hydrogen bonding between C-H in DMSO and oxygen atom in D_2O, a phase change, pressure increase, et. Ab initio calculation results, forecasting the fequency shift of the C-H stretching vibration as C-H-O is interacting via hydrogen bonding, are discussed. The reorganization of the hydrogen-bond network or geometry may be responsible for spectral changes as the pressure was elevated.