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Rational Design of alpha-Fe2O3/Reduced Graphene Oxide Composites: Rapid Detection and Effective Removal of Organic Pollutants

机译:α-Fe2O3/还原氧化石墨烯复合材料的合理设计:快速检测和有效去除有机污染物

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摘要

alpha-Fe2O3/reduced graphene oxide (alpha-Fe2O3/rGO) composites are rationally designed and prepared to integrate organic pollutants detection and their photocatalytic degradation. Specifically, the composites are used as the substrate for surface-enhanced Raman scattering (SERS) to detect rhodamine 6G (R6G). Repeatable strong SERS signals could be obtained with R6G concentration as low as 10(-5) M. In addition, the substrate exhibits self-cleaning properties under solar irradiation. Compared with pure alpha-Fe2O3 and alpha-Fe2O3/rGO mechanical mixtures, the alpha-Fe2O3/rGO composites show much higher photocatalytic activity and much greater Raman enhancement factor. After 10 cycling measurements, the photodegradation rate of R6G could be maintained at 90.5%, indicating high stability of the photocatalyst. This study suggests that the alpha-Fe2O3/rGO composites would serve both as recyclable SERS substrate and as excellent visible light photocatalyst.
机译:合理设计和制备了α-Fe2O3/还原氧化石墨烯(α-Fe2O3/ rGO)复合材料,以整合有机污染物的检测及其光催化降解。具体而言,将复合材料用作表面增强拉曼散射(SERS)的底物,以检测罗丹明6G(R6G)。 R6G浓度低至10(-5)M时,可以获得可重复的强SERS信号。此外,基材在阳光照射下具有自清洁性能。与纯α-Fe2O3和α-Fe2O3/ rGO机械混合物相比,α-Fe2O3/ rGO复合材料显示出更高的光催化活性和更大的拉曼增强因子。经过10次循环测量,R6G的光降解率可以维持在90.5%,表明光催化剂具有很高的稳定性。这项研究表明,α-Fe2O3/ rGO复合材料既可以用作可回收的SERS底物,又可以用作出色的可见光光催化剂。

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