Texture, microstructure and geochemistry of magnetite from the Banduhurang uranium mine, Singhbhum Shear Zone, India - Implications for physico-chemical evolution of magnetite mineralization

摘要

The Singhbhum Shear Zone in eastern India is one of the largest repositories of uranium and copper in India. Besides uranium and copper, apatite-magnetite mineralization is widespread in this shear zone. This study aims at deciphering the physico-chemical evolution of magnetite mineralization in relation to progressive shearing integrating field relations, micro-textures, structures and compositions of magnetite in the Banduhurang uranium mine. Apatite-magnetite ores occur as discrete patches, tongues, and veins in the strongly deformed, fine grained quartzchlorite schist. Textures and microstructures of magnetite indicate at least three stages of magnetite formation. Coarsegrained magnetite (magnetite-1) with long, rotational, and complex strain fringes, defined by fibrous and elongate quartz, is assigned to a stage of pre-/early-shearing magnetite formation. Medium grained magnetite (magnetite-2), characterized by single non-rotational strain fringe equivalent to the youngest fringe of magnetite-1, grew likely at the mid-/late-stage of shearing. Fine grained magnetite (magnetite-3) is generally devoid of any pressure shadow. This indicates even a much later stage of formation of this magnetite, presumably towards the closing stage of shearing. Some of the magnetite-1 grains are optically heterogeneous with a dark, pitted Cr-Ti-bearing core overgrown by lighter, fresh rim locally containing pyrite, chalcopyrite, and chlorite inclusions. The cores are also locally characterized by high Al and Si content. Homogeneous magnetite-1 is optically and compositionally similar to the overgrowth of heterogeneous magnetite-1. This homogeneous magnetite-1 that grew as separate phase is contemporaneous with the overgrowth on pitted core of heterogeneous magnetite-1. Magnetite-2 is compositionally very similar to homogeneous magnetite-1, but is devoid of sulfide inclusion. Magnetite-3 is generally devoid of any silicate or sulfide inclusion and is most pure with least concentrations of trace/minor elements. The high Al and Si content in some magnetite can be explained by coupled substitution that involves substitution of Si~(4+) for Fe~(3+) in the tetrahedral sites and Fe ~(2+) for Fe~(3+) in the octahedral sites, with a simple substitution of Al~(3+) for Fe~(3+) in the octahedral sites. The mode of occurrences of apatite-magnetite ores indicates a predominantly hydrothermal origin of most magnetite. However, the Cr-Ti-bearing magnetite-1 cores and inferred mafic nature of the original protolith indicates that some magnetite was inherited from the original igneous rock. We propose that the pre-/early-shearing hydrothermal event of magnetite formation was associated with sulfide mineralization and alteration of existing magmatic magnetite. The second stage of magnetite formation at the mid-/late-stage of shearing was not associated with sulfide formation. Finally, fine-grained compositionally pure magnetite formed at the closing stage of shearing likely due to metamorphism of Fe-rich protolith.