Ultrasonic velocities, densities, and refractive indices of binary mixtures of polyethylene glycol 250 dimethyl ether with 1-propanol and with 1-butanol

摘要

Measurements of the ultrasonic velocity (u), density (ρ) and refractive index (n) for binary mixtures of polyethylene glycol 250 dimethyl ether with 1-propanol and 1-butanol have been made at three temperatures (T=293, 303 and 31 K) over the entire composition range in order to investigate the nature of intermolecular interactions between the components of these liquid mixtures. Various excess thermodynamic properties such as the excess ultrasonic velocity (Δu), deviation in isentropic compressibility (Δk _S), excess intermolecular free length (L-{\mathrm{f}}^{\mathrm{E}}), excess acoustic impedance (Z ~E), excess pseudo-Grüneisen parameter (Γ ~E), and molar refraction deviation (ΔR _m) were calculated using experimental values of the ultrasonic velocity, density and refractive index and were then represented with the Redlich-Kister polynomial equation. The observed excess deviation parameter values were explained on the basis of the strength of intermolecular interactions between the components of the mixtures. Estimations of the refractive index and ultrasonic velocity have also been made using various empirical relations and are discussed in terms of the average percentage deviations (APD).