Enthalpies of dilution of N,N'hexamethylenebisacetamide in pure water and aqueous solutions of alkali halide at 298.15 K

摘要

Enthalpies of dilution of N,N'hexamethylenebisacetamide in water and aqueous alkali halide solutions at the concentration of 0.150 mol. kg ~(-1) (approximately the concentration of physiological saline) have been determined by isothermal titration microcalorimetry at 298.15 K. The enthalpic interaction coefficients in the solutions have been calculated according to the excess enthalpy concept based on the calorimetric data. The values of enthalpic pair-wise interaction coefficients (h _2) of the solute in aqueous solutions of different salts were discussed in terms of the different alkali salt ions and weak interactions of the diluted component with coexistent species as well as the change in solvent structure caused by ions.