Synthesis and structural characterization of a new self-assembled disulfide linked meso-tetrakis-porphyrin macromolecular array

摘要

The synthesis of a new self-assembled porphyrin macrostructure based on disulfide bonds, is presented. This constitutes a new way to directly connect porphyrins in macromolecular arrays, to complement the usual methods of intermolecular hydrogen bonds and metal coordination bonding.