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首页> 外文期刊>Journal of Biofuels >Acid and Base Catalysed Transesterification of Used Vegetable (Gutter) and Non-Edible Oils to Fatty Acid Methyl Esters
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Acid and Base Catalysed Transesterification of Used Vegetable (Gutter) and Non-Edible Oils to Fatty Acid Methyl Esters

机译:废菜油和非食用油的酸和碱催化酯交换为脂肪酸甲酯

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摘要

Transesterification of oils to their corresponding fatty acids methyl esters (FAME) has recently been recognised as an easy and cost effective technology for biodiesel production, mainly on account of the desirable physiochemical properties of the biodiesel produced. In this study, Jatropha (Jatropha curcas), Karanja (Pongania pinnata), Linseed (Linum usitatissimum) and used vegetable oils (Gutter oil) biodiesel production was optimised. Two-stage catalytic process (acid esterification and base transesterification) were used and the effects of factors like catalyst concentration (%w/w) from 0.6% to 1.1%, molar ratio (6:1 to 12:1), temperature (60-70°C) and time (1-6h) were investigated. The optimal yields for Linseed oil, Jatropha, Karanja and Gutter oils were 88.7%, 96%, 92.41% and 96.10%, respectively. The physical properties were then determined and compared with ASTM standards. It was concluded that catalytic transesterification of all oils studied here were economically viable and could be commercialised.
机译:近年来,主要由于生产的生物柴油具有理想的理化特性,油被酯交换成其相应的脂肪酸甲酯(FAME)已被认为是一种简单且经济高效的生物柴油生产技术。在这项研究中,麻疯树(Jatropha curcas),卡拉汉(Pongania pinnata),亚麻籽(Linum usitatissimum)和废植物油(Gutter油)生物柴油的生产得到了优化。使用了两阶段催化过程(酸酯化和碱酯交换),催化剂浓度(%w / w)从0.6%至1.1%,摩尔比(6:1至12:1),温度(60)等因素的影响研究了(-70°C)和时间(1-6h)。亚麻子油,麻风树油,卡拉汉叶油和天沟油的最佳收率分别为88.7%,96%,92.41%和96.10%。然后确定物理性质,并与ASTM标准进行比较。结论是,本文研究的所有油的催化酯交换反应在经济上都是可行的,可以商业化。

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