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Thermal Degradation of LC Epoxy Thermosets

机译:LC环氧热固性塑料的热降解

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摘要

A novel liquid crystalline (LC)epoxy monomer was cured with different types of hardeners.The thermal-degradation properties of cured thermosets were evaluated by thermogravimetric (TG) analysis.Several widely used kinetic models were reviewed and used to fit the TG data.The experimental results showed that the methods from one constant heating rate are imsensitive to the magnitude of reaction order n.The Kissinger and Osawa methods from multiple processes would give more confident kinetic parameters in these observed systems.
机译:用不同类型的固化剂固化新型液晶(LC)环氧单体,通过热重(TG)分析评估固化的热固性塑料的热降解性能,审查了几种广泛使用的动力学模型,并拟合了TG数据。实验结果表明,一个恒定加热速率下的方法对反应阶数n不敏感。在多个过程中,采用Kissinger和Osawa的多种方法可以得到更可靠的动力学参数。

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