Effect of the Degree of crystallinity on the Formation of Radical Ions in Irradiated Isotactic Polystyrene

A.A.Zezin; V.I.Feldman; A.V.Egorov; N.A.Shmakova

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Effect of the Degree of crystallinity on the Formation of Radical Ions in Irradiated Isotactic Polystyrene

机译：结晶度对辐照等规聚苯乙烯中自由基离子形成的影响

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The role of supramolecular organizaton in the radiation chemistry of isotactic polystyrene (PS0 was studied.an increase in the degreeof crystallinity decrases the radiaiton hcemicla yield of paramagnetic species.It was found that the radiation stability of polystyrene with different supramolecular organizaton is determiend by the efficinecy fo formationof dimeric radical cations.

机译：研究了超分子有机化在全同立构聚苯乙烯（PS0）的辐射化学中的作用。结晶度的增加使顺磁性物种的辐射h缩率降低。形成二聚自由基阳离子。

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《Doklady Chemistry》 |2004年第0期|共5页
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A.A.Zezin; V.I.Feldman; A.V.Egorov; N.A.Shmakova;
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正文语种 eng
中图分类化学;
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1. Effect of the Degree of crystallinity on the Formation of Radical Ions in Irradiated Isotactic Polystyrene [J] . A.A.Zezin, V.I.Feldman, A.V.Egorov, Doklady Chemistry . 2004,第0期

机译：结晶度对辐照等规聚苯乙烯中自由基离子形成的影响
2. The influence of electron beam irradiation, plastic deformation, and re-irradiation on crystallinity degree, mechanical and sclerometric properties of GUR 1050 used for arthroplasty [J] . Barylski Adrian, Maszybrocka Joanna, Kupka Marian, Journal of Applied Polymer Science . 2016,第27a28期

机译：电子束辐照，塑性变形和再辐照对用于关节成形术的GUR 1050的结晶度，力学和硬度特性的影响
3. Melting and reorganization of the crystalline fraction and relaxation of the rigid amorphous fraction of isotactic polystyrene on fast heating (30,000 K/min) [J] . Minakov AA, Mordvintsev DA, Tol R, Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems . 2006,第1a2期

机译：快速加热（30,000 K / min）时等规聚苯乙烯的结晶部分熔融和重组，以及刚性无定形部分松弛
4. An ESR study and quantum-chemical calculations of alkyl radicals in the matrix of polycrystalline n-alkane irradiated at 77K: effects of intermolecular interactions and carbon chain length on the radical formation [C] . S. R. Allayarov, S. V. Konovalikhin, T. E. Chernysheva Asia Pacific Electron Paramagnetic Resonance/Electron Spin Resonance Symposium . 2002

机译：在77K照射的多晶正烷烃基质中烷基的ESR研究和量子化学计算：分子间相互作用和碳链长对自由基形成的影响
5. Anionic synthesis of highly isotactic polystyrene in the presence of lithium hydroxides or lithium alkoxides, and, Controlled "living" emulsion polymerization of methyl methacrylate by atom transfer radical polymerization. [D] . Makino, Takayuki. 1997

机译：在氢氧化锂或烷氧基锂的存在下阴离子合成高度全同立构的聚苯乙烯，以及通过原子转移自由基聚合进行甲基丙烯酸甲酯的受控“活”乳液聚合。
6. Effect of Irradiation and Detection of Long-Lived Polyenyl Radicals in Highly Crystalline Ultra-High Molar Mass Polyethylene (UHMMPE) Fibers [O] . Amanda L. Forster, Zois Tsinas, Mohamad Al-Sheikhly 2019

机译：高结晶超高摩尔质量聚乙烯（UHMMPE）纤维中长寿命聚乙烯基自由基的辐照和检测效果
7. Behavior of Radicals Produecd in Gamma-Ray Irradiated Isotactic Poly-4-methylpentene-1 with Different Degrees of Tacticity [O] . Naoshi KUSUMOTO, Kenji SHIRANO, Motowo TAKAYANAGI 1965

机译：γ射线照射的全同立构多种4-甲基戊烯-1的自由基产品的行为，具有不同程度的术语
8. Deformation Behavior of Isotactic Polystyrene [R] . Anderson, J. K., Cohen, R. E., Argon, A. S. 1988

机译：等规聚苯乙烯的变形行为

Effect of the Degree of crystallinity on the Formation of Radical Ions in Irradiated Isotactic Polystyrene

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