Submerged membrane coagulation hybrid system as pretreatment to organic matter removal from seawater

摘要

In this study, a commonly used ferric chloride was utilised as coagulant for removing organic compounds from seawater. More than 57% of dissolved organic carbon (DOC) was removed at optimum dosage of 3 mg Fe~(+3)/L The coagulation by FeCI_3 at optimum dosage could remove a majority (95%) of hydrophobic compounds. The results from Liquid Chromatography - Organic Carbon Detector showed that only <0.02 mg/L of hydrophobic compounds was found after coagulation. In addition, the modified fouling index decreased considerably from 15,848 s/L~2 with raw seawater to 3,025 s/L~2 with seawater after coagulation. In-line coagulation coupled with submerged membrane system (ICSMS) was also trialled. It is observed that critical flux was increased from 20 L/m~2·h in the conventional submerged membrane system to 55 L/m~2 h in ICSMS. The ICSMS could remain the high DOC removal efficiency (more than 70%) at filtration rate of 20 L/m~2 h when keeping the development of trans-membrane pressure was significant lower than that of conventional submerged membrane system.