PRE-TREATMENT OF CURRENCY PRINTING INK WASTEWATER THROUGH COAGULATION-FLOCCULATION PROCESS

摘要

Attempt has been made to study the treatability of printing ink wastewater generated from an Indian currency printing press using coagulation-flocculation process. Coagulant agents, viz. ferrous sulphate, ferric chloride, aluminium sulphate and polyaluminium chloride were studied to select the most suitable coagulant for effective treatment, and attain the optimum coagulant concentration. Cationic polyeletrolyte in conjunction with the most effective coagulant was also studied to assess its effect on floc settleability. Polyaluminium chloride (PAC) was found to be the most efficient coagulant, achieving removals of colour, suspended solids (SS), biochemical oxygen demand (BOD) and chemical oxygen demand (COD) of 95.9-96.5%, 96.5-97.0%, 61.3-65.8% and 54.8-61.8%, respectively at an optimum concentration of 1500 mg L~(-1). Other coagulants, viz. ferrous sulphate, ferric chloride and aluminium sulphate did not show substantial removals of colour, BOD and COD, except suspended solids in comparison to the performance of PAC. Cationic ploylectrolyte in combination with PAC at an optimum concentration of 1500 mg L~(-1) of PAC and 1.0 mg L~(-1) of polyelectrolyte further improved the removal efficiency of various parameters studied, in addition to improving the floc settling rate, and reduction in quantity of sludge generation. Effect of rapid mixing intensity expressed as mean temporal velocity gradient (G), and mixing time (t) on flocculation was also investigated. Rapid mixing at an impeller rotational speed (n) of 300 rpm and mixing time (t) of 60 sec indicated good floc formation, which resulted in achieving velocity gradient of 821 s~(-1), and was found to be an optimum combination. This was also indicated by relatively high settling velocity of sludge formed and low residual colour in the supernatant. However, slow mixing beyond 5 min, adopted after initial optimum rapid mixing, indicated negligible effect on flocculation.