Mineralogical characterization of the Tournemire argillite after in situ interaction with concretes

摘要

This study aims to investigate, through mineralogicai characterization (SEM, XRD) and mass-balance calculations, the effects of contact time, concrete types and presence of free water on the Tournemire argillite under in situ conditions. Three sampling zones from Excavation Disturbed Zone (EDZ) areas have been chosen: (1) dry contacts, collected at the tunnel masonry/argillite interface (contact time - 125 years), (2) wet contacts, taken close to drained areas below the tunnel roadbed in contact with the canal draining the Cernon fault water (contact time - 15 and 7 years) and at the tunnel masonry/argillite interface over 70 m from the Cernon fault (contact time -125 years). This study shows that:in the absence of water, no significant modification of argillite is observed after 125 years, except for pyrite dissolution and gypsumprecipitation.in the presence of water, precipitation of gypsum, recrystallization of mixed-layer clays, neoformation of zeolites and K-feldsparsovergrowths are observed. At the concrete/argillite interface near the Cernon fault, important dolomite neoformation and leachingof chlorite and kaolinite occur. These processes are enhanced with contact time, low flow rate and the nature of the concrete (compound cement Portland CEM II 32.5). Evidence for oxidation processes linked to the EDZ (pyrite oxidation, Fe-oxy-hydroxide andgypsum precipitation) is observed.