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Research of the possibility of synthesis the complex oxide with by structure of perovskite in the system La-Ce-Pr-Nd-Sm-Mn-O

机译:La-Ce-Pr-Nd-Sm-Mn-O体系中钙钛矿结构合成复合氧化物的可能性的研究

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The possibility of formation of the complex oxide with by structure of perovskite in the system La-Ce-Pr-Nd-Sm-Mn-O was studied the methods of X-Ray-structure and X-Ray-phase analysis, thermogravimetry and IR-spectroscopy. Is established, that as a result of interaction in system two cubic phases will be formed: the phase on the base of CeO_2 with constant lattice a=5.4(9) A and complex oxide with by structure of perovskite of the type of loparite and parameter a=5.40(7) A.
机译:研究了La-Ce-Pr-Nd-Sm-Mn-O体系中钙钛矿结构形成复合氧化物的可能性。研究了X射线结构和X射线相分析,热重分析和红外光谱的方法。光谱学。确定了由于在系统中相互作用而形成的两个立方相:以铈矿结构和参数的钙钛矿结构,在具有恒定晶格a = 5.4(9)A的CeO_2和复合氧化物的基础上形成的立方相a = 5.40(7)A。

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