Heterobimetallic compounds [Ru(η5-Cp)(dppf)X] (X = Cl, Br, I and N<sub>3</sub>): synthesis, electrochemical analysis, and the crystal structure of [Ru(η5-Cp)(dppf)I] [dppf = 1,1′-bis(diphenylphosphino)ferrocene]

Lilian A. Paim; Alzir A. Batista; Fabrícia M. Dias; Camilla C. Golfeto; Javier Ellena; Helmuth G. L. Siebald; J. D. Ardisson

首页> 外文期刊>Transition Metal Chemistry >Heterobimetallic compounds [Ru(η5-Cp)(dppf)X] (X = Cl, Br, I and N₃): synthesis, electrochemical analysis, and the crystal structure of [Ru(η5-Cp)(dppf)I] [dppf = 1,1′-bis(diphenylphosphino)ferrocene]

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Heterobimetallic compounds [Ru(η5-Cp)(dppf)X] (X = Cl, Br, I and N₃): synthesis, electrochemical analysis, and the crystal structure of [Ru(η5-Cp)(dppf)I] [dppf = 1,1′-bis(diphenylphosphino)ferrocene]

机译：异双金属化合物[Ru（η 5 -Cp）（dppf）X]（X = Cl，Br，I和N _{3 ）：合成，电化学分析和晶体[Ru（η 5 -Cp）（dppf）I]的结构[dppf = 1,1'-双（二苯基膦基）二茂铁]}

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A series of new ruthenium-iron based derivatives [Ru(η5-Cp)(dppf)Cl] (1), [Ru(η5-Cp)(dppf)Br] (2), [Ru(η5-Cp)(dppf)I] (3) and [Ru(η5-Cp)(dppf)N₃] (4) were obtained by reactions of [Ru(η5-Cp)(PPh₃)₂Cl] with 1,1′-bis(diphenylphosphino) ferrocene (dppf) and characterized by IR, NMR (1H, 13C and 31P), 57Fe Mössbauer spectroscopy and cyclic voltammetry. Additionally, the compound (3) was structurally characterized by X-ray crystallography, and the results were as follows: orthorhombic, Pbca, a = 18.2458(10), b = 20.9192(11), c = 34.4138(19) Å, α = β = γ = 90°, V = 13135.3(12) Å3 and Z = 16.

机译：一系列新的钌铁基衍生物[Ru（η 5 -Cp）（dppf）Cl]（1），[Ru（η 5 -Cp）（dppf ）Br]（2），[Ru（η 5 -Cp）（dppf）I]（3）和[Ru（η 5 -Cp）（dppf）N _{3 ]（4）是通过[Ru（η 5 -Cp）（PPh _{3 ）_{2 Cl]，带有1,1'-双（二苯基膦基）二茂铁（dppf），并通过IR，NMR（ 1 H， 13 C和 31 P）， 57 FeMössbauer光谱和循环伏安法。另外，通过X射线晶体学对化合物（3）进行结构表征，结果如下：斜方晶，Pbca，a ＝ 18.2458（10），b ＝ 20.9192（11），c ＝ 34.4138（19）Å，α =β=γ= 90°，V = 13135.3（12）Å 3 和Z = 16。}}}

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《Transition Metal Chemistry 》 |2009年第8期| p.949-954| 共6页
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Lilian A. Paim; Alzir A. Batista; Fabrícia M. Dias; Camilla C. Golfeto; Javier Ellena; Helmuth G. L. Siebald; J. D. Ardisson;
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Heterobimetallic compounds [Ru(η5-Cp)(dppf)X] (X = Cl, Br, I and N3): synthesis, electrochemical analysis, and the crystal structure of [Ru(η5-Cp)(dppf)I] [dppf = 1,1′-bis(diphenylphosphino)ferrocene]

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Heterobimetallic compounds [Ru(η5-Cp)(dppf)X] (X = Cl, Br, I and N₃): synthesis, electrochemical analysis, and the crystal structure of [Ru(η5-Cp)(dppf)I] [dppf = 1,1′-bis(diphenylphosphino)ferrocene]