REACTIONS OF HETEROLEPTIC [Cu(acac)(AA)(H_2O)]~+ COMPLEXES WITH CARBOXYLATE ANIONS (acac~- = ACETYLACETONATE,AA = 2,2'-BIPYRIDINE, 1,10-PHENANTHROLINE)

Paul A. TARABUTA; Catalin MAXIM; Marius ANDRUH

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REACTIONS OF HETEROLEPTIC [Cu(acac)(AA)(H_2O)]~+ COMPLEXES WITH CARBOXYLATE ANIONS (acac~- = ACETYLACETONATE,AA = 2,2'-BIPYRIDINE, 1,10-PHENANTHROLINE)

机译：异致[Cu（Acac）（AA）（AA）（H_2O）]〜+络合物的反应（Acac〜=乙酰丙酮，AA = 2,2'-硼丙酮，1,10-菲咯啉）

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The reactions of [Cu(acac)(AA)(H_2O)]~+ species (AA = 2,2'-bipyridine, 1,10-phenanthroline) with anions derived from 4-methylphenol-2,6-dicarboxylic (H_3MeIPA) and isophthalic acids (H_2IPA) generate new complexes, which result by substituting the acetylacetonato ligand by carboxylato ones: [Cu(bipy)(HMeIPA)(H_2O)]·0.5H_2O·DMF 1 (DMF = dimethylformamide), ~1_∞[Cu(bipy)(IPA)(H_2O)_2]·H_2O·DMF 2, and ~1_∞[Cu(phen)(IPA)(H_2O)]·DMF 3. The crystal structures of 1-3 have been solved. Compound 1 is a mononuclear complex, while compounds 2 and 3 are one-dimensional coordination polymers with a zigzag topology.

机译：[Cu（ACAC）（AA）（H_2O）]〜+物种（AA = 2,2'-硼吡啶，1,10-菲咯啉）的反应，其阴离子衍生自4-甲基苯酚-2,6-二羧酸（H_3meipa）和中间邻苯二甲酸（H_2IPA）产生新的复合物，通过羧酸盐代替乙酰丙酮配体：[Cu（Bipy）（HmeIPA）（HmeIPA）]·0.5H_2O·DMF 1（DMF =二甲基甲酰胺），〜1-6 [Cu （Bipy）（IPA）（H_2O）_2]·H_2O·DMF 2，〜1_∞[Cu（Phen）（IPA）（IPA）（H_2O）]·DMF 3.已经解决了1-3的晶体结构。化合物1是单核复合物，而化合物2和3是具有锯齿形拓扑的一维配位聚合物。

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来源
《Revue roumaine de chimie》 |2021年第1期|41-472|共8页
作者
Paul A. TARABUTA; Catalin MAXIM; Marius ANDRUH;
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Inorganic Chemistry Laboratory Faculty of Chemistry University of Bucharest Str. Dumbrava Rosie nr. 23 Bucharest Roumania;

Inorganic Chemistry Laboratory Faculty of Chemistry University of Bucharest Str. Dumbrava Rosie nr. 23 Bucharest Roumania;

Inorganic Chemistry Laboratory Faculty of Chemistry University of Bucharest Str. Dumbrava Rosie nr. 23 Bucharest Roumania;

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正文语种 eng
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copper complexes; mixed-ligand complexes; carboxylato ligands; coordination polymers;

机译：铜复合物;混合配体复合物;羧盐配体;协调聚合物;

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专利

1. Diruthenium complexes [{(acac)(2)Ru-III}(2)(mu-OC2H5)(2)], [{(acac)(2)Ru-III}(2)(mu-L)](ClO4)(2), and [{(bpy)(2)Ru-II}(2)(mu-L)](ClO4)(4) [L=(NC5H4)(2)-N-C6H4-N-(NC5H4)(2), acac = acetylacetonate, and bpy=2,2 '-bipyridine]. Synthesis, structure, magn [J] . Kar S, Chanda N, Mobin SM, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2004,第16期

机译：钌络合物[{（acac）（2）Ru-III}（2）（mu-OC2H5）（2）]，[{（acac）（2）Ru-III}（2）（mu-L）]（ClO4 ）（2）和[{（bpy）（2）Ru-II}（2）（mu-L）]（ClO4）（4）[L =（NC5H4）（2）-N-C6H4-N-（ NC5H4）（2），acac =乙酰丙酮酸酯，bpy = 2,2'-联吡啶]。合成，结构，放大
2. Cr(AA)(C2O4)(2)](-) and [Cu(bpca)](+) as building blocks in designing new oxalato-bridged Cr-III-Cu-II compounds [AA=2,2 '-bipyridine and 1,10-phenanthroline; bpca = bis(2-pyridylcarbonyl)amide anion [J] . Lescouezec R., Marinescu G., Vaissermann J., Inorganica Chimica Acta . 2003,第0期

机译：Cr（AA）（C2O4）（2）[-]和[Cu（bpca）]（+）作为设计新草酸酯桥联的Cr-III-Cu-II化合物[AA = 2,2'-联吡啶1,10-菲咯啉bpca =双（2-吡啶基羰基）酰胺阴离子
3. Novel photo-induced deracemization of [Co(acac)(3)] (acac=acetylacetonate) with a chiral ruthenium(II) complex, Delta-[Ru(menbpy)(3)](2+) (menbpy=4,4 '-bis{(1R,2S,5R)-(-)-menthoxycarbonyl}-2,2 '-bipyridine). Reaction mechanism and significant effects [J] . Hamada T., Sakaki S., Ohtsuka H. Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 2001,第6期

机译：[Co（acac）（3）]（acac =乙酰丙酮酸）与手性钌（II）配合物Delta- [Ru（menbpy）（3）]（2+）的新型光诱导除铁（menbpy = 4,4 '-双{（（1R，2S，5R）-（-）-薄荷氧基羰基} -2,2'-联吡啶）。反应机理及显著作用
4. Electrochemistry Studies of UO_2(acac)_2L(acac = acetylacetonate, L = dimethyl sulfoxide, N,N-dimethylformamide, tetrahydrofuran) Complexes in Non-aqueous Solvents [C] . Seong-Yun Kim, Gunzo Uchiyama, Koichiro Mizuoka, International Symposium NUCEF . 2002

机译：UO_2（ACAC）_2L（ACAC =乙酰丙酮，L =二甲基亚甲醚，N，N-二甲基甲酰胺，四氢呋喃）复合物在非水溶剂中的电化学研究
5. Spectroscopic and Electrochemical Studies of [Ru(1,10-phenanthroline) 2(4,4'- dihydroxy-2,2'-bipyridine)]2+ and Related Complexes. [D] . Kuhn, Ashley E. 2017

机译：[Ru（1,10-phenothroline）2（4,4'-dihydroxy-2,2'-bipyridine）] 2+及其相关配合物的光谱和电化学研究。
6. Synthesis Structures and Properties of Cu(II) and Mn(II) Complexes with 110-Phenanthroline-2-carboxylic acid and 22’-Bipyridine Ligands [O] . Jingya Sun, Huanzhi Xu 2010

机译：110-菲咯啉-2-羧酸和22′-联吡啶配体的Cu（II）和Mn（II）配合物的合成结构和性能
7. Copper(II) solvatochromic complexes Cu(acac)(N^N)(ligand)BPh4 with various axial ligands. Correlation between coordination geometries and d–d transition energies (acac=acetylacetonato, N^N=1,10-phenanthoroline, 2,2′-bipyridyl) [O] . Horikoshi Ryo, Funasako Yusuke, Yajima Takeshi, 2013

机译：具有各种轴向配体的铜（II）溶剂变色配合物Cu（acac）（N ^ N）（配体） BPh4。配位几何与d–d跃迁能之间的相关性（acac =乙酰丙酮，N ^ N = 1,10-菲咯啉，2,2'-联吡啶）
8. Electropolymerization of Ruthenium Bis(1,10-phenanthroline)(4-methyl-4'vinyl-2,2'-bipyridine) Complexes through Direct Attack on the Ligand Ring System [R] . Guarr, T. F., Anson, F. C. 1987

机译：直接攻击配体环系统对双（1,10-菲咯啉）（4-甲基-4'-乙烯基-2,2'-联吡啶）配合物的电聚合

REACTIONS OF HETEROLEPTIC [Cu(acac)(AA)(H_2O)]~+ COMPLEXES WITH CARBOXYLATE ANIONS (acac~- = ACETYLACETONATE,AA = 2,2'-BIPYRIDINE, 1,10-PHENANTHROLINE)

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