Synthesis, Crystal Structure, and Luminescent Properties of Two Ternary Complexes with Mixed Thiocyanate and Quinoline Ligands

摘要

Two ternary complexes [Cu(NCS)₂(ql)₂] (ql = quinoline) (1) and [Zn(NCS)₂(ql)₂] (2) from SCNa?? and quinoline were synthesized and characterized by IR, UV, elemental analysis and X-ray crystallography. For two complexes, metal atom occupies a four-coordinated distorted tetrahedral environment bound to N atoms from two NCSa?? and two quinoline ligands. The molecule is held together with its neighboring ones via ??a???? stacking interactions to form a 1D structure. The luminescent properties of the complexes 1- 2 at room temperature were investigated.View full textDownload full textKeywordscrystal structure, luminescent properties, ternary complexRelated var addthis_config = { ui_cobrand: "Taylor & Francis Online", services_compact: "citeulike,netvibes,twitter,technorati,delicious,linkedin,facebook,stumbleupon,digg,google,more", pubid: "ra-4dff56cd6bb1830b" }; Add to shortlist Link Permalink http://dx.doi.org/10.3109/10799890903555624