Synthesis, Crystal Structure, and Luminescent Property of One 2D Silver(I) Coordination Polymer with Naphthalene-2,3-Dicarboxylate Ligand

摘要

A two-dimensional (2-D) coordination polymer, {[Ag(L)](H₂O)}_n (1) (L = naphthalene-2,3-dicarboxylate), was synthesized and structurally characterized by single crystal X-ray diffraction analysis. This complex belongs to orthorhombic system with space group Pca2₁, and exhibits a binodal 4-connected (44?·62)₂ topological net. In addition, such 2-D layers are further interlinked by the inter-layer C-H?·?·?·?? interactions, generating an overall 3-D supramolecular framework. Studies on photoluminescent property of 1 show the solid-state emission originating from an intraligand ??a????* transition of L ligand.View full textDownload full textKeywordscrystal structure, luminescence, naphthalene-2, 3-dicarboxylate, silver(I) complex, topologyRelated var addthis_config = { ui_cobrand: "Taylor & Francis Online", services_compact: "citeulike,netvibes,twitter,technorati,delicious,linkedin,facebook,stumbleupon,digg,google,more", pubid: "ra-4dff56cd6bb1830b" }; Add to shortlist Link Permalink http://dx.doi.org/10.1080/15533174.2011.568441