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Time- and space-resolved high energy operando X-ray diffraction for monitoring the methanol to hydrocarbons reaction over H-ZSM-22 zeolite catalyst in different conditions

机译:时间和空间分辨高能操作X射线衍射,用于监测H-ZSM-22沸石催化剂在不同条件下甲醇与烃的反应

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摘要

The conversion of methanol to hydrocarbons (MTH) over H-ZSM-22 was studied by operando time- and space-resolved X-ray diffraction (XRD) at 370-385 degrees C and WHSV = 2 g/g hat the Swiss-Norwegian Beamline at ESRF. The performance of a commercial H-ZSM-22 sample was compared before and after acid-base treatment, and with and without propanol co-feed, respectively.
机译:通过操作时间和空间分辨X射线衍射(XRD)在370-385摄氏度,WHSV = 2 g / g的条件下研究了H-ZSM-22甲醇转化为烃(MTH)的过程ESRF的光束线。在酸碱处理之前和之后,以及有和没有丙醇共同进料的情况下,分别比较了商业H-ZSM-22样品的性能。

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