Uniformly dispersed PtNi alloy nanoparticles in porous N-doped carbon nanofibers with high selectivity and stability for hydrogen peroxide detection

摘要

Highly dispersed Pt-based nanoparticles with superior electrocatalytic selectivity and stability are urgently needed for non-enzymatic electrochemical detection of H2O2. Herein, we prepared PtNi alloy nanoparticles dispersed in N-doped carbon nanofibers (PtNi/NCNFs) by pyrolyzing electrospun nanofibers composites from polyvinyl pyrrolidone and Pt/Ni-based salts. Characterization results indicated that PtNi alloy nanoparticles (average 9.0 nm) were homogeneously dispersed and embedded in NCNFs porous matrix. The electrochemical tests suggested that PtNi/NCNFs(3:1) displayed the highest electrocatalytic activity for H2O2reduction compared with Pt/NCNFs, Ni/NCNFs and other PtNi/NCNFs samples. PtNi/NCNFs(3:1)-based sensor showed excellent analytical properties towards H2O2with wide linear range (0.5 μM–8 mM), high sensitivity (248.5 μA mM−1 cm−2), low detection limit (0.0375 μM), high selectivity and anti-interference, attributing to the highly dispersion of nanoparticles and synergistic effect between PtNi alloy nanoparticles and NCNFs. The PtNi/NCNFs-based sensor had superior reproducibility due to the uniformity of PtNi/NCNFs and good stability because of the embedded structure, which prevented the aggregation and detachment of nanoparticles during repeated uses. More interestingly, the as-fabricated sensor displayed satisfactory recoveries and relative standard deviation (RSD) for detection of H2O2in milk samples. The above results manifested that PtNi/NCNFs had potential to be selected as a candidate for fabricating non-enzymatic H2O2sensors.