Application of chemically synthesized conducting polymer-polypyrrole as a carbon dioxide gas sensor

摘要

A polypyrrole (PPy) has been a subject of many studies because it exhibits relatively high electrical conductivity, good environmental stability and versatility of synthesis. Pyrrole (Py), the monomer of PPy, has been polymerized via chemically oxidative polymerization in the presence of an oxidant (FeCl_3. Two samples of PPy in the form of odorless black powder were prepared by taking the weight ratios of Py to FeCl_3 of 0.429 (low) and 4.290 (high). At both ratios, the concentration of oxidant was kept constant. PPy-Ⅰ sensor using PPy powder of a Py/FeCl_3 weight ratio of 0.429 and PPy-Ⅱ sensor using PPy powder of a Py/FeCl3 weight ratio of 4.290 were prepared by screen-printing technique on a glass substrate. For electrical contacts, electrodes of conducting silver paint were printed on adjacent sides of the sensor film. PPy-Ⅰ and PPy-Ⅱ sensors were used for CO_2 gas sensing investigation. Sensitivity of sensors at different concentrations of CO_2 gas was measured by a voltage drop method at room temperature (303 K). At certain higher concentration of CO_2 gas, a saturation effect was observed with both sensors. The response and recovery time were found short in PPy-Ⅱ sensor. XRD, SEM, FTIR and TG/DTA were used to analyze the PPy powder. In the π-orbital overlap of neighboring molecules of the PPy structure, the π-electrons delocalize along the entire chain, which provides semiconducting and conducting properties. CO_2 molecules formed weak bonds with TT-electrons of PPy. This causes an increase of resistance ofthe material in the presence of CO_2 gas.polypyrrole; chemical polymerization; screen-printing technique; carbon dioxide gas; π-electrons