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Carbon monoxide gas sensing properties of metal-organic frameworks-derived tin dioxide nanoparticles/molybdenum diselenide nanoflowers

机译:金属有机骨架衍生的二氧化锡纳米粒子/二硒化钼纳米花的一氧化碳气体传感特性

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A novel metal-organic frameworks-derived tin dioxide nanoparticles/molybdenum diselenide nanoflowers (SnO2/MoSe2) nanocomposite was designed by a facile hydrothermal method. Various characterization techniques demonstrated the successful preparation of the SnO2/MoSe2 nanostructures. The SnO2/MoSe2 composite with SnO2 and MoSe2 mass ratio of 4:1 exhibited a high response towards CO gas sensing at room temperature. The systematical gas sensing tests showed that the SnO2/MoSe2 composite at room temperature exhibited fast gas response/recovery speed, excellent repeatability, and anti-humidity interference for CO detection. It also showed an outstanding selectivity to CO against various potential interfering gases such as SO2, H2S, CH4, H-2 and CO2. Further studies indicated that the SnO2/MoSe2 nanocomposite improved CO gas performance due to the nn heterojunction formed at the interface between SnO2 nanoparticles and MoSe2 nanoflowers.
机译:通过简便的水热法设计了一种新颖的金属有机骨架衍生的二氧化锡纳米粒子/二硒化钼纳米花(SnO2 / MoSe2)纳米复合材料。各种表征技术证明了SnO2 / MoSe2纳米结构的成功制备。 SnO2和MoSe2质量比为4:1的SnO2 / MoSe2复合材料在室温下对CO气体感测显示出高响应性。系统的气敏测试表明,SnO2 / MoSe2复合材料在室温下表现出快速的气体响应/回收速度,出色的重复性和用于CO检测的抗湿干扰。它还对各种潜在的潜在干扰气体(例如SO2,H2S,CH4,H-2和CO2)具有出色的CO选择性。进一步的研究表明,由于在SnO2纳米颗粒和MoSe2纳米花之间的界面上形成了nn异质结,SnO2 / MoSe2纳米复合材料改善了CO气体性能。

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