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Mechanical and leaching behaviour of slag-cement and lime-activated slag stabilised/ solidified contaminated soil

机译:矿渣水泥和石灰活化矿渣稳定/固化的污染土壤的机械和浸出行为

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Stabilisation/solidification (S/S) is an effective technique for reducing the teachability of contaminants in soils. Very few studies have investigated the use of ground granulated blast furnace slag (GGBS) for S/S treatment of contaminated soils, although it has been shown to be effective in ground improvement. This study sought to investigate the potential of GGBS activated by cement and lime for S/S treatment of a mixed contaminated soil. A sandy soil spiked with 3000 mg/kg each of a cocktail of heavy metals (Cd, Ni. Zn, Cu and Pb) and 10,000 mg/kg of diesel was treated with binder blends of one part hydrated lime to four parts CGBS (lime-slag), and one part cement to nine parts GGBS (slag-cement). Three binder dosages, 5,10 and 20% (m/m) were used and contaminated soil-cement samples were compacted to their optimum water contents. The effectiveness of the treatment was assessed using unconfined compressive strength (UCS), permeability and acid neutralisation capacity (ANC) tests with determination of contaminant leachability at the different acid additions. UCS values of up to 800 kPa were recorded at 28 days. The lowest coefficient of permeability recorded was 5× 10~(-9) m/s. With up to 20% binder dosage, the leachability of the contaminants was reduced to meet relevant environmental quality standards and landfill waste acceptance criteria. The pH-dependent leachability of the metals decreased over time. The results show that GGBS activated by cement and lime would be effective in reducing the leachability of contaminants in contaminated soils.
机译:稳定化/固化(S / S)是一种有效的技术,可减少土壤中污染物的示教性。很少有研究研究使用磨碎的高炉矿渣(GGBS)对污染土壤进行S / S处理,尽管已证明它对改善土壤质量有效。这项研究试图研究水泥和石灰活化的GGBS在S / S处理混合污染土壤中的潜力。用一份熟石灰与四份CGBS(石灰)的粘合剂混合物处理掺有3000 mg / kg重金属(Cd,Ni,Zn,Cu和Pb混合物)和10,000 mg / kg柴油混合物的沙质土壤。 -渣)和一份水泥到九份GGBS(渣水泥)。使用了三种粘合剂剂量(5,10和20%(m / m)),并将受污染的土壤水泥样品压实至最佳含水量。使用无侧限抗压强度(UCS),渗透性和酸中和能力(ANC)测试评估了治疗的有效性,并确定了不同酸添加量下污染物的浸出能力。在28天时记录的UCS值高达800 kPa。记录的最低渗透率系数为5×10〜(-9)m / s。使用高达20%的粘合剂剂量,污染物的浸出性降低,以满足相关的环境质量标准和垃圾填埋场的接受标准。金属的pH依赖性浸出能力随时间降低。结果表明,水泥和石灰活化的GGBS可以有效降低污染物在污染土壤中的浸出能力。

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