Chemical composition and sources of submicron aerosol in a coastal city of China: Results from the 2017 BRICS summit study

摘要

Chemical compositions of non-refractory submicron aerosol (NR-PM,) were measured via an Aerodyne Aerosol Chemical Speciation Monitor at the coastal city Xiamen during the 2017 BRICS summit from August 10 to September 10. Mean hourly concentration of NR-PM, was 13.55 ± 8.83 μg m~3 during the study period, decreasing from 18.83 μg m~(-3) before-BRICS to 13.02 μg m~(-3) in BRCIS I and 8.42 μg m~(-3) in BRICS II. Positive matrix factor analyses resolved four organic aerosols (OA): a hydrocarbon-like OA (HOA, 14.78%), a cooking-related OA (COA 28.21%), a biomass burning OA (BBOA, 18.00%), and an oxygenated OA (OOA 39.22%). The contributions of local pollutants like nitrate and HOA reduced, while the proportions of sulfate and OOA increased during the control episodes. The diurnal patterns of NR-PM, species and OA components in each episode were characterized. The results showed that BC, nitrate, COA, and HOA had peaks in the morning and evening, which became less obvious under the emission control. Moreover, the diurnal variations of all species in Ep 3 with emission control were much flatter due to the effect of transport. Backward trajectories analysis confirmed the long-range transport of air masses from the continent, which resulted in the high proportions of sulfate (43.69%) and OOA (50.28%) in Ep 3. Our study implies the significant effect of emission control on reducing primary pollutants, but the formation of particles during the long-range transport need to be paid more attention when set the air quality control strategies in coastal cities.